Effects of postharvest pressure infiltration of distilled water, CaCl2 solutions at 0.14 or 0.27 mol·L-1 without and with subsequent fruit coating treatments of preclimacteric `Golden Delicious' [Malus sylvestris (L.) Mill. var. domestica (Borkh.) Mansf. `Golden Delicious'] apples on volatile levels, respiration, ethylene production, and internal atmospheres after storage at 0 °C for 1 to 6 months, and during subsequent shelf life at 20 °C were investigated. Over 30 volatiles were detected, most of the identified volatiles were esters; the rest were alcohols, aldehydes, ethers, a ketone, and a sesquiterpene. Pressure infiltration of water and increasing concentrations of CaCl2 resulted progressively in reduced total volatile levels, respiration, ethylene production, and internal O2 levels and increased CO2 levels in fruit following 2 to 4 months storage in air at 0 °C. Total volatile levels, respiration, ethylene production, and internal atmospheres of CaCl2-treated apples at 0.14 mol·L-1 gradually recovered to nontreated control levels following 2 weeks of shelf life at 20 °C and/or storage at 0 °C in air for more than 4 months. Following the calcium treatments with a shellac- or wax-based coating had similar but stronger and more persistent effects on volatile levels, respiration, ethylene production, and internal atmospheres than those found in fruit treated with CaCl2 alone. Calcium infiltration did not change the composition of volatile compounds found in fruit. Results suggest that pressure infiltration of `Golden Delicious' apples with CaCl2 solutions transiently inhibited volatile levels, respiration, and ethylene production, in part, by forming a more-or-less transient barrier to CO2 and O2 exchange between the fruit tissue and the surrounding atmosphere.