Photodegradation of FeDTPA in Nutrient Solutions. I. Effects of Irradiance, Wavelength, and Temperature

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  • 1 U.S. Department of Agriculture, Agricultural Research Service, 2001 S. Rock Road, Fort Pierce, FL 34945
  • | 2 Department of Horticulture, Box 340375, Clemson University, Clemson, SC 29634-0375

Irradiation of FeDTPA-containing nutrient solutions by a fluorescent plus incandescent light source resulted in the loss of both Fe-chelate and soluble Fe, the formation of a precipitate that was composed mostly of Fe, and a rise in pH. The rate of Fe-chelate photodegradation in solution increased with irradiance intensity and with solution temperature under irradiation, but irradiance had the greater effect. Fe-chelates absorb in the blue and UV regions of the spectrum. Removal of these wavelengths with a spectral filter eliminated photodegradation. Chemical name used: ferric diethylenetriaminepentaacetic acid (FeDTPA).

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